赵万祥，男，博士，湖南大学化学化工学院、化学生物传感与计量学国家重点实验室教授、博士生导师。2014年博士毕业于香港科技大学，2014-2017先后在密歇根大学（安娜堡分校）John Montgomery教授课题组和犹他大学《JACS》主编Peter Stang教授课题组从事博士后工作。2017年入选第十三批海外高层次人才计划。研究方向为有机方法学、金属有机化学、超分子化学、材料化学。

人物经历

- 2007.09-2010.07 硕士研究生 华东师范大学（导师：张俊良教授）

- 2011.02-2014.02 博士研究生 香港科技大学（导师：孙建伟教授）

- 2014.02-2016.02 密歇根大学 博士后研究（博士后合作导师：John Montgomery）

- 2016.03-2017.03 犹他大学 博士后研究（博士后合作导师：Peter Stang）

- 2017.03-至今 任教于湖南大学化学化工学院

研究领域

赵万祥教授的研究领域涵盖了金属有机化学、有机合成方法学、超分子化学等多个方面。

发表论文

以通讯作者和第一作者在《Nat. Chem.》《J. Am. Chem. Soc》《Angew. Chem. Int. Ed》 等期刊发表高水平论文40余篇，部分论文如下：

Zhao, W.; Montgomery, J.* Cascade 铜Catalyzed 1,2,3 Trifunctionalization of Terminal Allenes J. Am. Chem. Soc., 2016, 138, 9763-9766.

Zhao, W.; Montgomery, J.* Functionalization of Styrenes via Copper-Catalyzed Borylation/ortho-Cyanation and Silver-Catalyzed Annulation Processes Angew. Chem. Int. Ed, 2015, 54, 12683-12683.

Zhao, W.; Wang, Z.; Chu, B.; Sun, J*. Enantioselective Formation of All-碳 Quaternary Stereocenters from Indoles and Tertiary Alcohols Bearing A Directing Group Angew. Chem., Int. Ed. 2015, 54, 1910-1913 (Highlighted in SynFact).

Zhao, W.; Qian, H.; Li, Z*.; Sun, J.* Catalytic Ring Expansion of Cyclic Hemiaminals for the Synthesis of Medium Ring Lactams Angew. Chem. Int. Ed. 2015, 54, 10005-10008.

Zhao, W.; Li, Z.; Sun, J*. A New Strategy for Efficient Synthesis of Medium and Large Ring Lactones without High Dilution or Slow Addition J. Am. Chem. Soc. 2013, 135, 4680-4683.

Zhao, W.; Wang, Z.; Sun, J*. Synthesis of 8-Membered Lactones via Intermolecular [6+2] Cyclization of New Amphoteric Molecules with Siloxy Alkynes. Angew. Chem. Int. Ed. 2012, 51, 6209-6213.

Mixed Valence BN-Doped 心环烯 Trimer Radical Cations Yapei Gao, Zheming Liu, Tao Li*, and Wanxiang Zhao*, Angew. Chem. Int. Ed. 2023, 62, e202314006.

钴Catalyzed Asymmetric Remote Borylation of Alkyl Halides Minghao Zhang,# Zhiyang Ye,# and Wanxiang Zhao*, Angew. Chem. Int. Ed. 2023, 62, e202306248.

铑Catalyzed Remote Borylation of Alkynes and Vinylboronates Minghao Zhang, Zheming Liu, and Wanxiang Zhao*, Angew. Chem. Int. Ed. 2023, 62, e202215455.

Asymmetric Oxidative Lactonization of Enynyl Boronates Kezhuo Zhang#, Chenchen Li#, Yining Jia, and Wanxiang Zhao*, Angew. Chem. Int. Ed. 2022, 61, e202209004.

Enantioselective 钴Catalyzed Hydroboration of Ketone-Derived Silyl Enol Ethers Wenke Dong, Zhiyang Ye, and Wanxiang Zhao*, Angew. Chem. Int. Ed. 2022, 61, e2021174.

铑Catalyzed Regioselective and Chemoselective Deoxygenative Reduction of 1,3-Diketones Bing Zhang,§ Xueying Guo,§ Lei Tao, Ruolin Li, Zhenyang Lin,* and Wanxiang Zhao*, ACS Catal. 2022, 12, 4640-4647.

Enantioselective Rh-Catalyzed Hydroboration of Silyl Enol Ethers Wenke Dong,# Xin Xu,# Honghui Ma, Yaqin Lei, Zhenyang Lin, and Wanxiang Zhao*, J. Am. Chem. Soc. 2021, 143, 10902-10909.

铑Catalyzed Regiodivergent Synthesis of Alkylboronates via Deoxygenative Hydroboration of Aryl Ketones:Mechanism and Origin of Selectivities Bing Zhang,§ Xin Xu,§ Lei Tao, Zhenyang Lin,* and Wanxiang Zhao*, ACS Catal. 2021, 11, 9495-9505.

Stereodefined tetraarylethylenes: Synthesis and applications Minghao Zhang and Wanxiang Zhao*, Aggregate. 2021;2:E60

铑Catalyzed Deoxygenation and Borylation of Ketones: A Combined Experimental and Theoretical Investigation Lei Tao,∇ Xueying Guo,∇ Jie Li, Ruoling Li, Zhenyang Lin,* and Wanxiang Zhao*, J. Am. Chem. Soc. 2020, 142, 18118-18127.

Divergent and Stereoselective Synthesis of Tetraarylethylenes from Vinylboronates Minghao Zhang, Yisen Yao, Peter J. Stang* and Wanxiang Zhao*, Angew. Chem. Int. Ed. 2020, 59, 20090-20098.

Oxidation of Alkynyl Boronates to Carboxylic Acids, Esters and Amides Chenchen Li, Pei Zhao, Ruoling Li, Bing Zhang, and Wanxiang Zhao*, Angew. Chem. Int. Ed. 2020, 59, 10913-10917.

铑‐Catalyzed Remote C(sp3)−H Borylation of Silyl Enol Ethers Jie Li, Shuanglin Qu, and Wanxiang Zhao*, Angew. Chem. Int. Ed. 2020, 59, 2360-2364.

Formation of a Supramolecular Polymeric Adhesive via 液态水Participant 氢 Bonding Formation Qiao Zhang,⊥ Tao Li,⊥ Abing Duan,⊥ Shengyi Dong,* Wanxiang Zhao,* and Peter J. Stang*, J. Am. Chem. Soc. 2019, 141, 8058-8063.

Triflimide (HNTf2) in Organic Synthesis Wanxiang Zhao and Jianwei Sun*, Chem. Rev. 2018, 118, 10349-10392.

参考资料

赵万详.湖南大学.2024-04-02